Grain-scale iron isotopic distribution of pyrite from Precambrian shallow marine carbonate revealed by a femtosecond laser ablation multicollector ICP-MS technique: Possible proxy for the redox state of ancient seawater     

Manabu Nishizawa  Hiroki Yamamoto  Subaru Tsuruoka  Yusuke Sawaki  Yoshiaki Kon  Tsuyoshi Komiya  Takafumi Hirata 《Geochimica et cosmochimica acta》2010,74(9):2760-8899

The redox state of Precambrian shallow seas has been linked with material cycle and evolution of the photosynthesis-based ecosystem. Iron is a redox-sensitive element and exists as a soluble Fe(II) species or insoluble Fe(III) species on Earth’s surface. Previous studies have shown that the iron isotopic ratio of marine sedimentary minerals is useful for understanding the ocean redox state, although the redox state of the Archean shallow sea is poorly known. This is partly because the conventional bulk isotope analytical technique has often been used, wherein the iron isotopic record may be dampened by the presence of isotopically different iron-bearing minerals within the same sample. Here we report a microscale iron isotopic ratio of individual pyrite grains in shallow marine stromatolitic carbonates over geological time using a newly developed, near-infrared femtosecond laser ablation multicollector ICP-MS technique (NIR-fs-LA-MC-ICP-MS).We have determined that the grain-scale iron isotopic distribution of pyrite from coeval samples shows a bimodal (2.7 and 2.3 Ga) or unimodal pattern (2.9, 2.6, and 0.7 Ga). In particular, pyrite from the 2.7 Ga Fortescue Group shows a unique bimodal distribution with highly positive (+1.0‰ defined as Type 1) and negative δ⁵⁶Fe values (−1.8‰ defined as Type 2). Type 1 and 2 pyrites occasionally occur within different siliceous layers in the same rock specimen. Layer-scale iron isotopic heterogeneity indicates that the iron isotopic ratios of the two types of pyrite are not homogenized by diagenesis after deposition. Some cubic pyrites have a core with a positive δ⁵⁶Fe value (1‰) and a rim with a crustal δ⁵⁶Fe value (0‰). The observed isotopic zoning suggests that the positive δ⁵⁶Fe value is a primary signature at the time of stromatolite formation, while secondary pyrite precipitated during diagenesis.The positive δ⁵⁶Fe value of Type 1 and the large iron isotopic difference between Type 1 and 2 (2.8‰.) suggest partial Fe(II) oxidation in the 2.7-Ga shallow sea, i.e., pyritization of ⁵⁶Fe-enriched ferric oxyhydroxide (Type 1) and ⁵⁶Fe depleted Fe²⁺aq in seawater (Type 2). Type 2 pyrite was probably not produced by microbial iron redox cycling during diagenesis because this scenario requires a higher abundance of pyrite with δ⁵⁶Fe of 0‰ than of −1.8‰. Consequently, the degree of Fe(II) oxidation in the 2.7-Ga shallow sea can be estimated by a Fe²⁺aq steady-state model. The model calculation shows that half the Fe²⁺aq influx was oxidized in the seawater. This implies that O₂ produced by photosynthesis would have been completely consumed by oxidation of the Fe²⁺aq influx. Grain-scale iron isotopic distribution of pyrite could be a useful index for reconstructing the redox state of the Archean shallow sea.  相似文献   

A method for estimating casualties due to the tsunami inundation flow     

Shunichi Koshimura  Toshitaka Katada  Harold O. Mofjeld  Yoshiaki Kawata 《Natural Hazards》2006,39(2):265-274

This study develops a method for estimating the number of casualties that may occur while people evacuate from an inundation zone when a tsunami has inundated an area. The method is based on a simple model of hydrodynamic forces as they affect the human body. The method uses a Tsunami casualty index (TCI) computed at each grid point of a numerical tsunami model to determine locations and times within the tsunami inundation zone where evacuation during the tsunami inundation is not possible and therefore where casualties are likely to occur. The locations and times can be combined with information about population density to compute the potential number of casualties. This information is useful in developing tsunami evacuation routes that avoid such locations. To illustrate the method, it is applied to the Seattle waterfront in Washington State, USA, that is under the threat of possible tsunami disasters due to Seattle Fault earthquakes. Preliminary results suggest that the tsunami casualties may occur within the Seattle waterfront for 15 min, during the time interval from 3 to 18 min after a large Seattle Fault tsunami is generated when the background tide level is mean high water.  相似文献   

Evaluation of groundwater resources in wide inundation areas of the Mekong River basin   总被引：2，自引：0，他引：2  

So Kazama  Terumichi Hagiwara  Priyantha Ranjan  Masaki Sawamoto 《Journal of Hydrology》2007,340(3-4):233-243

Severe floods can have disastrous impacts and cause wide ranging destruction in the Mekong River basin. At the same time groundwater resources are significantly influenced and extensively recharged by flood water in inundation areas of the basin. This study determines the variation of groundwater resources caused by flooding over inundated areas located in lower part of the Mekong River basin using numerical modeling and field observations. The inundation calculations have been evaluated using satellite image outputs. Comparing large, medium and small flood events, we conclude that flood control which reduces the area of inundation, results in a reduction of groundwater resources in the area. In 1993, a 19% reduction in inundation areas resulted in a 31% reduction in groundwater storage. In 1998, a 44% reduction in inundation areas led to a 42% reduction in groundwater storage. Thus, while flood control activities are vital to reduce negative flood impacts in the Mekong River basin, they also negatively impact groundwater resources in the area.  相似文献   

Photometric properties of the Arp 220 super star clusters     

Yasuhiro Shioya  Yoshiaki Taniguchi  Neil Trentham 《Monthly notices of the Royal Astronomical Society》2001,321(1):11-17

We investigate the photometric properties of six super stellar clusters (SSCs) seen in both the optical and near-infrared Hubble Space Telescope images of the local ultraluminous starburst galaxy Arp 220. Three of the SSCs are located in the central 0.5-kpc region. The remaining three are in the circumnuclear region between 0.5 and 2.5 kpc from the centre. Comparing the observed spectral energy distributions (SEDs) of the SSCs with the Starburst99 models of Leitherer et al., we confirm that all three nuclear SSCs are heavily obscured     Considering the results from this comparison in conjunction with measurements of the near-infrared CO absorption index and of millimetre CO linewidths and luminosities, we estimate the ages of the nuclear SSCs to be 10⁷–10⁸ yr. The bolometric luminosity of the three nuclear SSCs is at most one-fifth of the total bolometric luminosity of Arp 220. On the other hand, the circumnuclear SSCs have little internal extinction     These contribute negligibly to the total bolometric luminosity.  相似文献   

Continuous Measurements of Ground-Water Seepage Using an Automatic Seepage Meter   总被引：6，自引：1，他引：6  

Makoto Taniguchi  Yoshiaki Fukuo 《Ground water》1993,31(4):675-679

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Propagation of slip along frictional surfaces     

Yoshiaki Ida 《Pure and Applied Geophysics》1978,116(4-5):943-953

The propagation of slip along a pre-existing frictional plane is formulated for the faults containing interstitial fluid. When normal and shear stresses satisfy the effective frictional law, a frictional sliding occurs stably or unstably, depending on the inhomogeneities of the surface. For a slip to rapidly sweep the surface, the pore pressure of fluid must exceed the critical value that is related to the physical or geometrical irregularities of the surface. If this condition fails, stable sliding is expected, analogous to a seismic fault creep. This prediction makes the role of water in seismic faulting more clear.  相似文献   

Interionic repulsive force and compressibility of ions     

Yoshiaki Ida 《Physics of the Earth and Planetary Interiors》1976,13(2):97-104

The compressibility of an individual ion is examined, in comparison with a known set of data for the alkali halides. A simple extrapolation of ionic radius to high pressure is not acceptable, because the pressure derivative of ionic radius changes for different salts. According to the classical concept of an elastic ion, the repulsive potential energy between the ions i and j is specified by the nature of each ion as: as a function of the interionic distance r. In this expression, q_i and ρ_i are the ionic radius and ionic compressibility, respectively, in a suitably modified meaning. Such a form of the repulsive potential fits well to the data of lattice constants and bulk moduli. The parameters q_i and ρ_i are evaluated for alkali and halogen ions, and an anion turns out to be much more compressible than a cation. The present treatment may be usefully applied to the minerals in the Earth's mantle, which contain only a few major ions.  相似文献   

Probability of earthquake occurrence as obtained from a Weibull distribution analysis of crustal strain   总被引：2，自引：0，他引：2  

Yukio Hagiwara 《Tectonophysics》1974,23(3):313-318

Probability of a large-scale earthquake occurrence is estimated from crustal strain geodetically detected over an earthquake area. The Weibull distribution function, which is widely applied to quality-control research, is made use of in this paper in the probabilistic treatments of crustal strain.Using the table of ultimate strain presented by Rikitake (1974), a Weibull model representing a statistical distribution of crustal-rupture occurrence time is determined on the assumption that the crust is strained with a constant speed. In the case of the South Kanto District, the associated probability-density function has a maximum at about 84 years after the time when the strain energy accumulation starts.  相似文献   

Damage to coastal villages due to the 1992 Flores Island earthquake tsunami     

Yoshinobu Tsuji  Hideo Matsutomi  Fumihiko Imamura  Minoru Takeo  Yoshiaki Kawata  Masafumi Matsuyama  Tomoyuki Takahashi  Sunarjo  Prih Harjadi 《Pure and Applied Geophysics》1995,144(3-4):481-524

A field survey of the 1992 Flores Island earthquake tsunami was conducted during December 29, 1992 to January 5, 1993 along the north coast of the eastern part of Flores Island. We visited over 40 villages, measured tsunami heights, and interviewed the inhabitants. It was clarified that the first wave attacked the coast within five minutes at most of the surveyed villages. The crust was uplifted west of the Cape of Batumanuk, and subsided east of it. In the residential area of Wuring, which is located on a sand spit with ground height of 2 meters, most wooden houses built on stilts collapsed and 87 people were killed even though the tsunami height reached only 3.2 meters. In the two villages on Babi Island, the tsunami swept away all wooden houses and killed 263 of 1,093 inhabitants. Tsunami height at Riang-Kroko village on the northeastern end of Flores Island reached 26.2 meters and 137 of the 406 inhabitants were killed by the tsumani. Evidence of landslides was detected at a few points on the coast of Hading Bay, and the huge tsunami was probably formed by earthquake-induced landslides. The relationship between tsunami height and mortality was checked for seven villages. The efficiencies of trees arranged in front of coastal villages, and coral reefs in dissipating the tsunami energy are discussed.  相似文献   

Internal structures and U–Pb ages of zircons from a tuff layer in the Meishucunian formation, Yunnan Province, South China     

Yusuke Sawaki  Manabu Nishizawa  Takeshi Suo  Tsuyoshi Komiya  Takafumi Hirata  Naoto Takahata  Yuji Sano  Jian Han  Yoshiaki Kon  Shigenori Maruyama 《Gondwana Research》2008,14(1-2):148

The Precambrian/Cambrian (PC/C) boundary is one of the most important intervals for the evolution of life, represented by prominent biological evolution from the first appearance of soft-bodied animals from the late Neoproterozoic to the sudden diversification of animals with mineralized skeletons in the Cambrian. In South China several areas contain many fossils and are well exposed, suitable for the investigation of PC/C boundary. However, geochronological relationships are still poorly known because of lack of combined detailed investigations of internal structures of zircons and in-situ U–Pb dating.We focus on the internal structure of zircons from a tuff layer within Bed 5 in the Meishucun section on which we undertook cathodoluminescence (CL) imaging and in-situ U–Pb dating with LA-ICP-MS and nano-SIMS. Over 600 zircons from the tuff layer were classified into three types based on their CL images: oscillatory rims, inherited cores and dull structures. U–Pb dating of the internal structure of the zircons by LA-ICP-MS clearly shows a distinct unimodal age population dependent on the structure: 531 ± 17 Ma for the oscillatory rims and 515 Ma for the dull structures. The clear oscillatory zonation, the prismatic morphology, and their occurrence indicate that the oscillatory rims were formed from felsic magmatism, and that the U–Pb nano-SIMS age of 536.5 ± 2.5 Ma records the depositional age of the tuff. Our results indicate that the PC/C boundary is situated below Bed 5, and therefore the bottom of Zone 1 (Marker A) is more appropriate for the PC/C boundary than is the top of Zone 1 (Marker B). The age of a positive anomaly (P2) in the early Cambrian is estimated to be ca. 536 Ma.  相似文献